Diaquabis(1-methyl-1H-imidazole-κN 3)bis[2-(naphthalen-1-yl)acetato-κO]cobalt(II)
نویسندگان
چکیده
In the title compound, [Co(C(12)H(9)O(2))(2)(C(4)H(6)N(2))(2)(H(2)O)(2)], the Co(II) ion is located on an inversion centre and displays a distorted octa-hedral coordination geometry. Two O atoms from two water mol-ecules and two carboxyl-ate O atoms from two 2-(naphthalen-1-yl)acetate ligands are in the equatorial plane and two N atoms from two 1-methyl-1H-imidazole ligands are in the axial positions. The structure is stabilized by intra-molecular O-H⋯O hydrogen bonds. Inter-molecular O-H⋯O hydrogen bonds link the complex mol-ecules into chains along [100].
منابع مشابه
Bis(1-methyl-1H-imidazole-κN 3)bis[2-(naphthalen-1-yl)acetato-κO]copper(II) monohydrate
In the crystal structure of the title compound, [Cu(C(12)H(9)O(2))(2)(C(4)H(6)N(2))(2)]·H(2)O, the Cu(II) atom is coordinated by two 2-(naphthalen-1-yl)acetate anions and two 1-methyl-imidazole ligands, giving monomeric complexes with a square-planar coordination environment. Two complex mol-ecules and two water mol-ecules form a centrosymmetric ring system via O-H⋯O hydrogen bonds.
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